Welcome to H4O!
Start with fluids, lots of them! Oil, transfer case, noting that some 06 models have a different fill procedure (Dexron VI), both diffs (synthetic 75W-90), transmission with at least a drain and fill with new filter and gasket (Dexron VI), brake fluid (DOT3), coolant flush (Dexcool). Plugs are 100K miles and it's probably 50/50 whether they were ever done.
Check for play at the transmission crossmember - is the bushing worn out? After that, upper and lower control arm bushings and ball joints. Serpentine belt, idler, tensioner (great kit available on rockauto.com).
Put in in 4Low range and test that it engages. Then test the rear locker, even if turning on pavement (but better on dirt!) for a moment to see if the rear axle binds/locks.